How do I change the binding order for multiple network adapters or add a second IP address to my network adapter?

From the Run line:

To change the binding order of network adapters:

  1. Click Start, click Run, type ncpa.cpl, and then click OK. You can see the available connections in the LAN and High-Speed Internet section of the Network Connections window.
  2. On the Advanced menu, click Advanced Settings, and then click the Adapters and Bindings tab.
  3. In the Connections area, select the connection that you want to move higher in the list. Use the arrow buttons to move the connection.

To add multiple IP addresses to a single network card:

  1. Click Start, click Run, type ncpa.cpl , and then click OK. The available connections appear in the LAN and High-Speed Internet section of the Network Connections window.
  2. Right-click the network adapter that you want to change, click Properties, and then click the General tab.
  3. In the This connection uses the following items box, select Internet Protocol (TCP/IP). Then, click Properties.
  4. In the Internet Protocol (TCP/IP) Properties dialog box, click the General tab, and then click Advanced.
  5. On the IP Settings tab, click to clear the Automatic metric check box. Then, type a value in the Interface metric box.

From Control Panel:

  1. Click Start, point to Settings, and then click Control Panel.
  2. Double-click Network and Dial-up Connections.
  3. On the Advanced menu, click Advanced Settings.
  4. In the Connections box, select the adapter you want to change the binding order on. After you select the adapter, the Bindings for Local Area Connection box display the current binding order.
  5. Use the arrows on the right-side of the box to move the protocol you choose to the top of the list, and then click OK.
  6. If you are prompted to restart the computer, click Yes.